Hearts 5 Hibs 1 at Hampden, 2012
England 0 Scotland 1 at Wembley, 1999
Hearts 2 Rangers 1 at Parkhead, 1998
Hearts 2 Aberdeen 1 at Hampden, 1996
Rangers 0 Hearts 3 at Ibrox, 1996

Loads of wins against Celtic too. Every single one of them special.